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If you only have one disk in the NAS then removing it will remove the all the DSM setup: there isn't some flash storage on the circuit board that holds DSMs, only the loader that gets the NAS up and running.
Each disk that's in the NAS will be formatted and configured with a small(ish) partition that holds DSM: you can then lose any disk and DSM [should] still run. But the remaining large part of the disk will be assigned to storage: this will then be available for making a storage pool (or storage pools). A storage pool can then hold one or more volumes. The default installation is to take all installed disks and make one storage pool (SHR-1 or SHR-2) with one volume.
The volume will then be used to hold Shared Folders (look in Control Panel and Edit a storage pool: see how you can change which volume it is on, if you have another volume) and Packages. Unlike Shared Folders, Package Center's setting doesn't allude to the fact that they are installed on a volume until you have more than one volume. Then there will be an option to set which volume to install Packages and their data, or it will ask each time you install a package.
Also unlike Storage Pools, there is no simple [documented] way to move a package and it's data to another volume once it has been installed. A google will throw up some methods that rely on SSH access.
As for not losing the current single disk SHR setup then you have two options:
- Add a second drive of the same or larger size and make the SHR into 'with 1 disk redundancy', similar to RAID 1.
- Make a Hyper Backup archive and then rebuild the NAS and restore from the archive.