it is not so easy as was explained
OP doesn’t mentioned file system used:
- when ext4, you can easy rebuild you superblock. Problem is when some inodes are corrupted, even directory entries. Synology DSM can’t handle it by itself. Reallocating of data from the blocks can be contra productive by FS, when their content is actually overwritten by OS. Better is use method - unmount the drives from the NAS and run it externally with fsck.ext4 or from Win with HDsentinel to check it in better way
- when btrfs it is even worse. because btrfs doesn’t track bad blocks. Additionally, scrub could be taught to test for bad blocks when a checksum error is found. This would make scrub much more useful; checksum errors are generally caused by the disk, but while scrub detects afflicted files, which in a backup scenario gives the opportunity to recreate them, the next file to reuse the bad blocks will just start getting errors instead.
From all the aspect. Damaged block and new HDD is not good start and you need to check them out if the NAS.
just to be sure